Ireland has a lower opportunity cost for the production of glass than Luxembourg does; therefore, Ireland has a comparative advantage in the production of glass. That is, Ireland has to give up only 6 pairs of boots to produce a pane of glass while Luxembourg must give up 11 pairs of boots to produce a pane of glass. Another way to think of it is that it is cheaper for Ireland to produce glass than it is for Luxembourg. Therefore, it is better for Ireland to specialize in the production of glass.
You can determine the opportunity cost of boots in terms of glass from the opportunity cost of glass in terms of boots. For example, Ireland's opportunity cost of producing a pane of glass is 6 pairs of boots. Therefore, Ireland can produce 6 pairs of boots if it forgoes the production of 1 pane of glass. This means that Ireland's opportunity cost of producing a pair of boots is 1/6 of a pane of glass. Similarly, Luxembourg's opportunity cost of producing a pane of glass is 11 pairs of boots, so Luxembourg's opportunity cost of producing a pair of boots is 1/11 of a pane of glass. Since Luxembourg has a lower opportunity cost for the production of boots than Ireland does, it has a comparative advantage in the production of boots.